\u4e2d\u6587\u540d<\/b><\/strong><\/span><\/td>\n1,8-\u4e8c\u6c2e\u6742\u4e8c\u73af\u5341\u4e00\u78b3-7-\u70ef<\/span><\/td>\n | \u5316\u5b66\u5f0f<\/b><\/strong><\/span><\/td>\nC9H16N2<\/span><\/td>\n<\/tr>\n\n\u5916\u6587\u540d<\/b><\/strong><\/span><\/td>\n1,8-Diazabicyclo[5.4.0]undec-7-ene\uff08DBU\uff09<\/span><\/td>\n | \u5206\u5b50\u91cf<\/b><\/strong><\/span><\/td>\n152.24<\/span><\/td>\n<\/tr>\n\nCAS\u767b\u5f55\u53f7<\/b><\/strong><\/span><\/td>\n6674-22-2<\/span><\/td>\n | CAS\u767b\u5f55\u53f7<\/b><\/strong><\/span><\/td>\n6674-22-2<\/span><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n <\/p>\n <\/p>\n \u5236\u5907<\/b><\/strong><\/span><\/p>\n\u5408\u6210DBU\u7684\u4e00\u822c\u65b9\u6cd5\u662f\u5df1\u5185\u9170\u80fa\u4e0e\u4e19\u70ef\u8148\u4eb2\u6838\u52a0\u6210\u751f\u6210N-(2-\u6c30\u57fa\u4e59\u57fa)\u5df1\u5185\u9170\u80fa\uff0c\u7ecf\u50ac\u5316\u52a0\u6c22\u5f97N-(3-\u6c28\u57fa\u4e19\u57fa)\u5df1\u5185\u9170\u80fa\uff0c\u8131\u6c34\u73af\u5408\u5f97\u5230DBU\uff0c\u5728\u5408\u6210N-(3-\u6c28\u57fa\u4e19\u57fa)\u5df1\u5185\u9170\u80fa\u65f6\uff0c\u4e00\u822c\u4e0d\u4f7f\u7528\u6eb6\u5242\uff0c\u64cd\u4f5c\u7b80\u5355\uff0c\u4f46\u4e0d\u6613\u63a7\u5236\u53cd\u5e94\u6e29\u5ea6\uff0c\u5e38\u4ea7\u751f\u5927\u91cf\u7684\u805a\u5408\u7269\u3002\u5728\u5408\u6210DBU\u65f6\uff0c\u901a\u5e38\u9700\u8981\u5728\u538b\u529b\u4e0b\u50ac\u5316\u52a0\u6c22\uff0c\u5bf9\u53cd\u5e94\u8bbe\u5907\u8981\u6c42\u8f83\u9ad8\u3002<\/span><\/p>\n<\/p>\n \u5e94\u7528<\/b><\/strong><\/span><\/p>\nDBU\u662f\u4e00\u4e2a\u5f3a\u78b1\u6027\u8bd5\u5242\uff0c\u4f46\u5b83\u5374\u662f\u4e00\u4e2a\u5f31\u7684\u4eb2\u6838\u8bd5\u5242\uff0c\u6613\u4e0e\u8d28\u5b50\u7ed3\u5408\u800c\u4e0d\u6613\u4e0e\u78b3\u539f\u5b50\u7ed3\u5408\uff0c\u56e0\u6b64DBU\u7684\u5e94\u7528\u4e3b\u8981\u662f\u4f5c\u4e3a\u5f3a\u78b1\u6027\u8bd5\u5242\u8f6c\u79fb\u8d28\u5b50\uff0c\u8d77\u5230\u78b1\u6216\u50ac\u5316\u5242\u7684\u4f5c\u7528\u3002DBU\u53c2\u4e0e\u53cd\u5e94\u7684\u7279\u70b9\u662f\uff0c\u4e00\u822c\u9700\u8981\u7b49\u7269\u8d28\u7684\u91cf\u7684DBU\uff0c\u5e94\u7528\u7684\u53cd\u5e94\u4e5f\u4e3b\u8981\u96c6\u4e2d\u5728\u6709\u8d28\u5b50\u8f6c\u79fb\u7684\u4e00\u4e9b\u53cd\u5e94\uff0c\u5982\u6d88\u9664\u3001\u5f02\u6784\u3001\u52a0\u6210\u3001\u916f\u5316\u3001\u919a\u5316\u3001\u9170\u80fa\u5316\u3001\u91cd\u6c2e\u5316\u7b49\u53cd\u5e94\u3002<\/span><\/p>\n1.\u6d88\u9664\u53cd\u5e94<\/b><\/strong><\/span><\/p>\nDBU\u5df2\u88ab\u5e94\u7528\u5230\u591a\u79cd\u6d88\u9664\u53cd\u5e94\u4e2d\uff0c\u4f7f\u8bd5\u5242\u5206\u5b50\u5f15\u5165\u4e0d\u9971\u548c\u952e\uff0c\u4f5c\u4e3a\u6709\u673a\u5408\u6210\u7684\u4e2d\u95f4\u4f53\u548c\u539f\u6599\uff0c\u4ec5\u4e3e\u51e0\u4e2a\u4f8b\u5b50\u5c31\u8db3\u4ee5\u770b\u5230DBU\u5728\u6d88\u9664\u53cd\u5e94\u65b9\u9762\u7684\u5e94\u7528\u3002<\/span><\/p>\n1\uff09\u5364\u4ee3\u70f7\u6d88\u9664\u5364\u5316\u6c22<\/span><\/p>\n\u5178\u578b\u7684\u53cd\u5e94\u662f1\uff0c1-\u4e8c\u7898\u4e01\u70f7\u4e0e\u7b49\u7269\u8d28\u7684\u91cf\u7684DBU\u4e00\u8d77\u52a0\u70ed\u56de\u6d41\u81f3\u51fa\u73b0\u68d5\u8272\u56fa\u4f53\uff0c\u4ece\u53cd\u5e94\u6df7\u5408\u7269\u4e2d\u84b8\u998f\u5206\u79bb\u5f97\u5230\u4ea7\u7269(E)-1-\u7898-1-\u4e01\u70ef\uff0c\u4ea7\u7387\u4e3a80%\u3002\u901a\u5e38DBU\u96be\u4ee5\u4f7f\u4e59\u70ef\u57fa\u5364\u5316\u7269\u8131\u5364\u5316\u6c22\u751f\u6210\u7094\u70c3\uff0c\u4f46\u662f\u7279\u6b8a\u7ed3\u6784\u7684(E)-\u4e59\u70ef\u57fa\u6eb4\u548cDBU\u5728\u4e2d\u56de\u6d41\uff0c\u51e0\u4e4e\u5b9a\u91cf\u5730\u8f6c\u5316\u4e3a\u76f8\u5e94\u7684\u7094\uff0c\u800c(Z)-\u5f0f\u5f02\u6784\u4f53\u5374\u4e0d\u80fd\u53d1\u751f\u6b64\u7c7b\u53cd\u5e94\u3002\u7528DBU\u4f7f\u5364\u70c3\u8131\u5364\u5316\u6c22\u7684\u4f8b\u5b50\u5f88\u591a\uff0c\u8db3\u4ee5\u8bf4\u660eDBU\u662f\u4e00\u79cd\u5f88\u6709\u6548\u7684\u5364\u4ee3\u70f7\u8131\u5364\u5316\u6c22\u8bd5\u5242\u3002<\/span><\/p>\n2)N-\u5364\u4ee3\u9170\u80fa\u6d88\u9664\u5364\u5316\u6c22<\/span><\/p>\n\u5728DBU\u4f5c\u7528\u4e0b\uff0cN-\u5364\u4ee3\u9170\u80fa\u80fd\u987a\u5229\u5730\u8131\u53bb\u5364\u5316\u6c22\uff0c\u968f\u540e\u91cd\u6392\u6210\u5f02\u6c30\u9178\u916f\uff0cN-\u6c2f\u4ee3\u7532\u9170\u80fa\u5728DBU\u7684\u4f5c\u7528\u4e0b\uff0c\u91cd\u6392\u5f97\u5230\u5f02\u6c30\u9178\u916f\uff0c\u6536\u7387\u8fbe\u523090%\u4ee5\u4e0a\u3002\u800c\u7528\u4e09\u4e59\u80fa\u4e4b\u7c7b\u7684\u6709\u673a\u78b1\u4ee3\u66ffDBU\uff0c\u96be\u4ee5\u5f97\u5230\u5f02\u6c30\u9178\u916f\u3002<\/span><\/p>\n <\/p>\n 2.\u5f02\u6784\u53cd\u5e94<\/b><\/strong><\/span><\/p>\n\u53cc\u952e\u5f02\u6784\u548c\u5dee\u5411\u5f02\u6784\u53cd\u5e94\u5728\u6709\u673a\u5408\u6210\u4e2d\u6781\u5176\u6709\u7528\uff0cDBU\u5728\u8fd9\u79cd\u5f02\u6784\u53cd\u5e94\u4e2d\u90fd\u5177\u6709\u826f\u597d\u7684\u50ac\u5316\u4f5c\u7528\u3002<\/span><\/p>\n1\uff09\u53cc\u952e\u5f02\u6784\u53cd\u5e94<\/span><\/p>\n\u5229\u7528DBU\u53ef\u4ee5\u5c06\u03b2\uff0c\u03b3-\u4e0d\u9971\u548c\u916f\u7c7b\u5316\u5408\u7269\u8f6c\u53d8\u6210\u76f8\u5e94\u7684\u03b1\uff0c\u03b2-\u4e0d\u9971\u548c\u916f\u3002\u5728DBU\u4f5c\u7528\u4e0b\uff0c60%\u76843-\u620a\u70ef\u9178\u916f\u5f02\u6784\u6210\u7a33\u5b9a\u76842-\u620a\u70ef\u9178\u916f\uff1b\u5728\u50ac\u5316\u5242DBU\u4f5c\u7528\u4e0b\uff0c\u03b2\uff0c\u03b3-\u4e0d\u9971\u548c\u8148\u4e5f\u80fd\u5f02\u6784\u6210\u7a33\u5b9a\u7684\u03b1\uff0c\u03b2-\u4e0d\u9971\u548c\u8148\u3002<\/span><\/p>\n2\uff09\u5dee\u5411\u5f02\u6784\u53cd\u5e94<\/span><\/p>\n\u7acb\u4f53\u5f02\u6784\u4f53\u6df7\u5408\u7269\u548cDBU\u5728\u5ba4\u6e29\u4e0b\u53cd\u5e941h\uff0c\u5176\u987a\u5f0f-3\uff0c4-\u5f02\u6784\u4f53\u8f6c\u5316\u6210\u53cd\u5f0f-3\uff0c4-\u5f02\u6784\u4f53\uff0c\u9009\u62e9\u6027\u4e3a96%\u3002\u8fd9\u5bf9\u5408\u6210\u7279\u6b8a\u6784\u578b\u5316\u5408\u7269\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b9\u6cd5\u3002<\/span><\/p>\n <\/p>\n 3.DBU\u505a\u4e3a\u78b1\u6027\u8bd5\u5242\u8131\u03b1-H\u4ea7\u751f\u78b3\u8d1f\u79bb\u5b50\u4e2d\u95f4\u4f53\u7684\u53cd\u5e94<\/b><\/strong><\/span><\/p>\nDBU\u662f\u4f7f\u5177\u6709\u6d3b\u6cfc\u03b1-\u6c22\u5316\u5408\u7269\u8131\u53bb\u8d28\u5b50\u5f62\u6210\u78b3\u8d1f\u79bb\u5b50\u7684\u78b1\u6027\u8bd5\u5242\uff0c\u5176\u4e2d\u4ee5Michael\u52a0\u6210\u53cd\u5e94\u4e3a\u5178\u578b\uff0c\u5176\u53cd\u5e94\u6761\u4ef6\u6e29\u548c\uff0c\u526f\u53cd\u5e94\u5c11\u3002\u5728\u73af\u5df1\u916e\u7532\u9178\u916f\u548c\u4e19\u70ef\u9178\u7532\u916f\u53cd\u5e94\u4e2d\uff0c\u4ee5DBU\u505a\u78b1\u6027\u8bd5\u5242\uff0c\u5f97\u5230\u4ea7\u7269\uff0c\u6536\u7387\u4e3a96%\u3002<\/span><\/p>\nDBU\u4f7f\u785d\u57fa\u5316\u5408\u7269\u4e0e\u542b\u53cc\u952e\u7684\u4e59\u70ef\u57fa\u916e\u53d1\u751fMichael\u53cd\u5e94\uff0c\u4ea7\u7387\u4e3a95%\uff1b\u5316\u5408\u726915\u548c2-\u73af\u620a\u70ef\u916e\u53d1\u751fMichael\u53cd\u5e94\uff0c\u6c34\u89e3\u8131\u7fa7\u540e\u751f\u6210(+)-3-\u73af\u620a\u916e\uff0c\u603b\u4ea7\u7387\u4e3a43%\uff0c\u5149\u5b66\u7eaf\u5ea6\u8fbe96%\u3002\u800c\u7528\u4e09\u57fa\u9502\u6216\u53d4\u4e01\u6c27\u57fa\u94be\u4e3a\u50ac\u5316\u5242\u5f97\u5230\u4ea7\u7269\u7684\u4ea7\u7387\u867d\u7136\u63a5\u8fd1\uff0c\u4f46\u5149\u5b66\u7eaf\u5ea6\u5374\u4f4e\u5f97\u591a\uff0c\u4ec5\u4e3a7%\uff5e76%\u3002\u6b64\u5916\uff0c\u5728\u4e19\u4e8c\u9178\u548c\u5df1\u919b\u53d1\u751f\u7684Knovenagel\u7f29\u5408\u53cd\u5e94\u4e2d\uff0c\u7528DBU\u505a\u78b1\u6027\u8bd5\u5242\uff0c\u572890\u2103\u4e0b\u53cd\u5e9410h\uff0c\u5f97\u5230\u03b2\uff0c\u03b3-\u4e0d\u9971\u548c\u5f02\u6784\u4f53\u7684\u9009\u62e9\u6027\u4e3a94%\uff0c\u4ea7\u7387\u4e3a56%\u3002<\/span><\/p>\n\u00a0<\/b><\/strong><\/span><\/p>\n4.\u916f\u5316\u3001\u919a\u5316\u3001\u9170\u80fa\u5316\u53cd\u5e94<\/b><\/strong><\/span><\/p>\nDBU\u53ef\u7528\u505a\u4ece\u7fa7\u9178\u3001\u5364\u70c3\u5236\u5907\u916f\u3001\u80fa\u7c7b\u5316\u5408\u7269\u53ca\u4ece\u9187\u5236\u5907\u919a\u3001\u916f\u548c\u6c28\u57fa\u7532\u9178\u916f\u7b49\u5316\u5408\u7269\u7684\u50ac\u5316\u5242\u3002\u8fd9\u7c7b\u53cd\u5e94\u662f\u901a\u8fc7\u7fa7\u9178\u6216\u9187\u4e0e\u70f7\u57fa\u5364\u5316\u7269\u3001\u9170\u57fa\u5316\u5242\u6216\u8005\u5176\u4ed6\u4eb2\u7535\u8bd5\u5242\u8131\u8d28\u5b50\u800c\u6210\uff0c\u5176\u4e2d\u916f\u5316\u548c\u9170\u80fa\u5316\u53cd\u5e94\u4e00\u822c\u5728\u5ba4\u6e29\u4e0b\u5373\u53ef\u8fdb\u884c\uff0c\u800c\u919a\u5316\u53cd\u5e94\u4e00\u822c\u572860\uff5e80\u2103\u4e0b\u8fdb\u884c\u3002<\/span><\/p>\n <\/p>\n 5.\u73af\u52a0\u6210\u53cd\u5e94<\/b><\/strong><\/span><\/p>\n\u5728\u5408\u62102\uff0c5-\u4e8c\u7532\u57fa-3-\u57fa-2-\u73af\u620a\u70ef\u916e\u65f6\uff0c\u5229\u7528DBU\u4f5c\u50ac\u5316\u5242\uff0c\u4ea7\u7387\u8fbe\u523070%\u3002\u5728\u5408\u6210\u56db\u6c22\u5421\u54af\u884d\u751f\u7269\u65f6\uff0c\u4e5f\u662f\u5229\u7528DBU\u4f5c\u50ac\u5316\u5242\u7ecf\u8fc7\u73af\u52a0\u6210\u800c\u5f97\u5230\u7684\uff0c\u4ea7\u7387\u4e5f\u8fbe90%\u4ee5\u4e0a\u3002<\/span><\/p>\n\u00a0<\/b><\/strong><\/span><\/p>\n6.\u91cd\u6c2e\u5316\u53cd\u5e94<\/b><\/strong><\/span><\/p>\n\u8fd1\u53d1\u73b0\uff0c\u5728\u5408\u6210\u03b1-\u91cd\u6c2e\u916e\u548c\u03b1-\u91cd\u6c2e\u916f\u7684\u53cd\u5e94\u4e2d\uff0cDBU\u6709\u5f88\u597d\u7684\u50ac\u5316\u4f5c\u7528\u3002\u5728DBU\u7684\u50ac\u5316\u4e0b\uff0c\u78fa\u9170\u53e0\u6c2e\u5316\u5408\u7269\u5bf9\u6709\u5173\u5316\u5408\u7269\u7684\u6d3b\u6027\u90e8\u4f4d\u8fdb\u884c\u91cd\u6c2e\u5316\u53cd\u5e94\uff0c\u6761\u4ef6\u6e29\u548c\uff0c\u4ea7\u7387\u9ad8\u3002<\/span><\/p>\n <\/p>\n","protected":false},"excerpt":{"rendered":" DBU\u7684\u5236\u5907\u4e0e\u5e94\u7528 \u80cc\u666f\u53ca\u6982\u8ff0 DBU\uff1a1\uff0c8-\u4e8c\u6c2e\u6742\u4e8c\u73af-\u53cc\u73af(5\uff0c4\uff0c0)-7-\u5341\u4e00\u70ef\uff0c\u662f\u4e00\u79cd\u53cc\u73af\u8112\u7c7b\u5316\u5408\u7269\uff0c\u5177\u6709\u5f3a\u78b1\u6027\u30022005\u5e74\u53d1\u8868\u5728nature\u4e0a\u7684\u4e00\u7bc7\u6587\u7ae0\u8868\u793a\uff0cDBU\u4f5c\u4e3a\u53ef\u8f6c\u6362\u6781\u6027\u6eb6\u5242\uff0c\u5e76\u53ef\u4f5c\u4e3a\u8403\u53d6\u5242\u5e94\u7528\u4e8e\u6cb9\u8102\u7684\u8403\u53d6\u64cd\u4f5c\u4e2d\uff0c\u8403\u53d6\u7387\u8f83\u9ad8\uff0c\u5728\u5206\u79bb\u7684\u8fc7\u7a0b\u4e2d\u53ea\u9700\u8981\u901a\u5165CO2\u4f7f\u8f6c\u53d8\u4e3a\u79bb\u5b50\u6db2\u4f53\u6781\u6027\u53d8\u9ad8\uff0c\u4f7f\u5f97\u6cb9\u5c42\u4e0e\u79bb\u5b50\u6db2 …<\/p>\n","protected":false},"author":1,"featured_media":4905,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[4],"tags":[1409],"_links":{"self":[{"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/posts\/4904"}],"collection":[{"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/comments?post=4904"}],"version-history":[{"count":2,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/posts\/4904\/revisions"}],"predecessor-version":[{"id":4908,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/posts\/4904\/revisions\/4908"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/media\/4905"}],"wp:attachment":[{"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/media?parent=4904"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/categories?post=4904"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/tags?post=4904"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}} | | | | | | | |