{"id":6205,"date":"2024-09-27T13:23:45","date_gmt":"2024-09-27T05:23:45","guid":{"rendered":"https:\/\/www.51dmea.cn\/archives\/6205"},"modified":"2024-09-27T13:23:45","modified_gmt":"2024-09-27T05:23:45","slug":"%e5%bc%82%e8%be%9b%e9%85%b8%e9%93%8b%e4%bd%9c%e4%b8%ba%e9%87%91%e5%b1%9e%e5%82%ac%e5%8c%96%e5%89%82%e5%9c%a8%e5%8c%96%e5%ad%a6%e5%b7%a5%e4%b8%9a%e4%b8%ad%e7%9a%84%e5%ba%94%e7%94%a8%e5%ae%9e%e4%be%8b","status":"publish","type":"post","link":"https:\/\/www.51dmea.cn\/archives\/6205","title":{"rendered":"\u5f02\u8f9b\u9178\u94cb\u4f5c\u4e3a\u91d1\u5c5e\u50ac\u5316\u5242\u5728\u5316\u5b66\u5de5\u4e1a\u4e2d\u7684\u5e94\u7528\u5b9e\u4f8b"},"content":{"rendered":"<h3 data-spm-anchor-id=\"5176.28103460.0.i7.297c5d279tXmt2\">\u5f02\u8f9b\u9178\u94cb\u4f5c\u4e3a\u91d1\u5c5e\u50ac\u5316\u5242\u5728\u5316\u5b66\u5de5\u4e1a\u4e2d\u7684\u5e94\u7528<\/h3>\n<h4>\u6458\u8981<\/h4>\n<p>\u5f02\u8f9b\u9178\u94cb\u662f\u4e00\u79cd\u91cd\u8981\u7684\u6709\u673a\u94cb\u5316\u5408\u7269\uff0c\u56e0\u5176\u72ec\u7279\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u5728\u5316\u5b66\u5de5\u4e1a\u4e2d\u88ab\u5e7f\u6cdb\u7528\u4f5c\u50ac\u5316\u5242\u3002\u672c\u6587\u7efc\u8ff0\u4e86\u5f02\u8f9b\u9178\u94cb\u4f5c\u4e3a\u91d1\u5c5e\u50ac\u5316\u5242\u5728\u4e0d\u540c\u5316\u5b66\u53cd\u5e94\u4e2d\u7684\u5e94\u7528\u5b9e\u4f8b\uff0c\u5305\u62ec\u4f46\u4e0d\u9650\u4e8e\u916f\u5316\u53cd\u5e94\u3001\u52a0\u6c22\u53cd\u5e94\u3001\u805a\u5408\u53cd\u5e94\u7b49\uff0c\u5e76\u5bf9\u5176\u50ac\u5316\u673a\u7406\u8fdb\u884c\u4e86\u7b80\u8981\u5206\u6790\u3002\u6b64\u5916\uff0c\u8fd8\u8ba8\u8bba\u4e86\u5f02\u8f9b\u9178\u94cb\u5728\u73af\u4fdd\u548c\u7ecf\u6d4e\u6027\u65b9\u9762\u7684\u4f18\u52bf\uff0c\u4ee5\u53ca\u672a\u6765\u7684\u7814\u7a76\u65b9\u5411\u3002<\/p>\n<h4>1. \u5f15\u8a00<\/h4>\n<p>\u968f\u7740\u7eff\u8272\u5316\u5b66\u6982\u5ff5\u7684\u63d0\u51fa\u548c\u53d1\u5c55\uff0c\u5bfb\u627e\u9ad8\u6548\u3001\u73af\u5883\u53cb\u597d\u578b\u50ac\u5316\u5242\u6210\u4e3a\u5316\u5b66\u5de5\u4e1a\u7814\u7a76\u7684\u91cd\u70b9\u4e4b\u4e00\u3002\u5f02\u8f9b\u9178\u94cb\u4f5c\u4e3a\u4e00\u79cd\u6027\u80fd\u4f18\u826f\u7684\u6709\u673a\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u56e0\u5176\u5177\u6709\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\u3001\u8f83\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u53ca\u9009\u62e9\u6027\uff0c\u5728\u591a\u4e2a\u9886\u57df\u5c55\u73b0\u51fa\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002\u672c\u6587\u65e8\u5728\u603b\u7ed3\u5f02\u8f9b\u9178\u94cb\u5728\u5316\u5b66\u5de5\u4e1a\u4e2d\u7684\u5178\u578b\u5e94\u7528\u6848\u4f8b\uff0c\u4e3a\u76f8\u5173\u9886\u57df\u7684\u7814\u7a76\u4eba\u5458\u63d0\u4f9b\u53c2\u8003\u3002<\/p>\n<h4>2. \u5f02\u8f9b\u9178\u94cb\u7684\u57fa\u672c\u6027\u8d28<\/h4>\n<ul>\n<li><strong>\u5316\u5b66\u5f0f<\/strong>\uff1aBi(Oct)3<\/li>\n<li><strong>\u5916\u89c2<\/strong>\uff1a\u767d\u8272\u6216\u5fae\u9ec4\u8272\u56fa\u4f53<\/li>\n<li><strong>\u6eb6\u89e3\u6027<\/strong>\uff1a\u6613\u6eb6\u4e8e\u9187\u7c7b\u3001\u916e\u7c7b\u7b49\u6709\u673a\u6eb6\u5242<\/li>\n<li><strong>\u70ed\u7a33\u5b9a\u6027<\/strong>\uff1a\u8f83\u9ad8<\/li>\n<\/ul>\n<h4>3. \u5e94\u7528\u5b9e\u4f8b<\/h4>\n<h5>3.1 \u916f\u5316\u53cd\u5e94<\/h5>\n<p>\u5f02\u8f9b\u9178\u94cb\u5728\u916f\u5316\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\uff0c\u80fd\u591f\u6709\u6548\u4fc3\u8fdb\u7fa7\u9178\u4e0e\u9187\u4e4b\u95f4\u7684\u53cd\u5e94\uff0c\u63d0\u9ad8\u76ee\u6807\u4ea7\u7269\u7684\u9009\u62e9\u6027\u548c\u4ea7\u7387\u3002\u4f8b\u5982\uff0c\u5728\u5408\u6210\u9999\u6599\u548c\u836f\u7269\u4e2d\u95f4\u4f53\u7684\u8fc7\u7a0b\u4e2d\uff0c\u4f7f\u7528\u5f02\u8f9b\u9178\u94cb\u4f5c\u4e3a\u50ac\u5316\u5242\u53ef\u4ee5\u663e\u8457\u7f29\u77ed\u53cd\u5e94\u65f6\u95f4\uff0c\u964d\u4f4e\u80fd\u8017\u3002<\/p>\n<h5>3.2 \u52a0\u6c22\u53cd\u5e94<\/h5>\n<p>\u5728\u52a0\u6c22\u53cd\u5e94\u4e2d\uff0c\u5f02\u8f9b\u9178\u94cb\u540c\u6837\u5c55\u73b0\u4e86\u5176\u72ec\u7279\u7684\u4f18\u52bf\u3002\u5b83\u80fd\u6709\u6548\u6d3b\u5316\u6c22\u5206\u5b50\uff0c\u4fc3\u8fdb\u6c22\u6c14\u4e0e\u4e0d\u9971\u548c\u5316\u5408\u7269\u4e4b\u95f4\u7684\u52a0\u6210\u53cd\u5e94\uff0c\u7279\u522b\u9002\u7528\u4e8e\u5236\u5907\u7cbe\u7ec6\u5316\u5b66\u54c1\u548c\u9ad8\u9644\u52a0\u503c\u6750\u6599\u3002\u5982\u5728\u5408\u6210\u805a\u6c28\u916f\u539f\u6599\u7684\u8fc7\u7a0b\u4e2d\uff0c\u91c7\u7528\u5f02\u8f9b\u9178\u94cb\u4f5c\u4e3a\u50ac\u5316\u5242\u53ef\u663e\u8457\u63d0\u5347\u4ea7\u54c1\u7684\u7eaf\u5ea6\u548c\u6536\u7387\u3002<\/p>\n<h5>3.3 \u805a\u5408\u53cd\u5e94<\/h5>\n<p>\u5f02\u8f9b\u9178\u94cb\u5728\u67d0\u4e9b\u7c7b\u578b\u7684\u805a\u5408\u53cd\u5e94\u4e2d\u4e5f\u53d1\u6325\u7740\u91cd\u8981\u4f5c\u7528\u3002\u6bd4\u5982\uff0c\u5728\u5236\u5907\u751f\u7269\u964d\u89e3\u5851\u6599\u65f6\uff0c\u5229\u7528\u5f02\u8f9b\u9178\u94cb\u4f5c\u4e3a\u5f15\u53d1\u5242\uff0c\u4e0d\u4ec5\u80fd\u591f\u63a7\u5236\u805a\u5408\u7269\u7684\u5206\u5b50\u91cf\u5206\u5e03\uff0c\u8fd8\u80fd\u6539\u5584\u6750\u6599\u7684\u673a\u68b0\u6027\u80fd\uff0c\u6ee1\u8db3\u7279\u5b9a\u5e94\u7528\u9700\u6c42\u3002<\/p>\n<h4>4. \u50ac\u5316\u673a\u7406\u7b80\u6790<\/h4>\n<p>\u5f02\u8f9b\u9178\u94cb\u4e4b\u6240\u4ee5\u80fd\u5728\u4e0a\u8ff0\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u826f\u597d\u7684\u50ac\u5316\u6548\u679c\uff0c\u4e3b\u8981\u5f52\u56e0\u4e8e\u5176\u7279\u6b8a\u7684\u7535\u5b50\u7ed3\u6784\u548c\u914d\u4f4d\u80fd\u529b\u3002\u5728\u50ac\u5316\u8fc7\u7a0b\u4e2d\uff0c\u5f02\u8f9b\u9178\u6839\u79bb\u5b50\u80fd\u591f\u4e0e\u53cd\u5e94\u5e95\u7269\u5f62\u6210\u7a33\u5b9a\u7684\u914d\u5408\u7269\uff0c\u964d\u4f4e\u53cd\u5e94\u7684\u6d3b\u5316\u80fd\uff0c\u4ece\u800c\u52a0\u901f\u53cd\u5e94\u8fdb\u7a0b\u3002\u540c\u65f6\uff0c\u94cb\u5143\u7d20\u81ea\u8eab\u7684Lewis\u9178\u6027\u4e5f\u6709\u52a9\u4e8e\u4fc3\u8fdb\u8d28\u5b50\u8f6c\u79fb\u7b49\u5173\u952e\u6b65\u9aa4\uff0c\u8fdb\u4e00\u6b65\u63d0\u9ad8\u4e86\u6574\u4f53\u7684\u50ac\u5316\u6548\u7387\u3002<\/p>\n<h4>5. \u4f18\u52bf\u4e0e\u6311\u6218<\/h4>\n<ul>\n<li><strong>\u73af\u4fdd\u4f18\u52bf<\/strong>\uff1a\u76f8\u6bd4\u4e8e\u4f20\u7edf\u91cd\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u5f02\u8f9b\u9178\u94cb\u6bd2\u6027\u8f83\u4f4e\uff0c\u6613\u4e8e\u56de\u6536\u5904\u7406\uff0c\u5bf9\u73af\u5883\u53cb\u597d\u3002<\/li>\n<li><strong>\u7ecf\u6d4e\u6548\u76ca<\/strong>\uff1a\u867d\u7136\u5f02\u8f9b\u9178\u94cb\u7684\u6210\u672c\u76f8\u5bf9\u8f83\u9ad8\uff0c\u4f46\u7531\u4e8e\u5176\u9ad8\u6548\u7684\u50ac\u5316\u6027\u80fd\uff0c\u53ef\u4ee5\u5728\u8f83\u4f4e\u7528\u91cf\u4e0b\u5b9e\u73b0\u7406\u60f3\u7684\u8f6c\u5316\u7387\uff0c\u4ece\u957f\u8fdc\u6765\u770b\u5177\u6709\u8f83\u597d\u7684\u7ecf\u6d4e\u6027\u3002<\/li>\n<li><strong>\u6311\u6218<\/strong>\uff1a\u5982\u4f55\u8fdb\u4e00\u6b65\u63d0\u9ad8\u5f02\u8f9b\u9178\u94cb\u7684\u7a33\u5b9a\u6027\u548c\u91cd\u590d\u4f7f\u7528\u6b21\u6570\uff0c\u51cf\u5c11\u50ac\u5316\u5242\u635f\u5931\uff0c\u4ecd\u662f\u672a\u6765\u7814\u7a76\u9700\u8981\u89e3\u51b3\u7684\u95ee\u9898\u3002<\/li>\n<\/ul>\n<h4>6. \u7ed3\u8bba<\/h4>\n<p>\u5f02\u8f9b\u9178\u94cb\u4f5c\u4e3a\u4e00\u79cd\u591a\u529f\u80fd\u7684\u6709\u673a\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u5728\u5316\u5b66\u5de5\u4e1a\u4e2d\u6709\u7740\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\u3002\u901a\u8fc7\u4e0d\u65ad\u4f18\u5316\u5176\u5408\u6210\u65b9\u6cd5\u548c\u4f7f\u7528\u6761\u4ef6\uff0c\u6709\u671b\u5728\u672a\u6765\u5f00\u53d1\u51fa\u66f4\u591a\u9ad8\u6548\u3001\u73af\u4fdd\u7684\u65b0\u5de5\u827a\uff0c\u63a8\u52a8\u5316\u5b66\u5de5\u4e1a\u5411\u66f4\u52a0\u53ef\u6301\u7eed\u7684\u65b9\u5411\u53d1\u5c55\u3002<\/p>\n<h4>7. \u8868\u683c\uff1a\u5f02\u8f9b\u9178\u94cb\u5728\u5316\u5b66\u5de5\u4e1a\u4e2d\u7684\u5e94\u7528\u5b9e\u4f8b<\/h4>\n<table>\n<thead>\n<tr>\n<th>\u53cd\u5e94\u7c7b\u578b<\/th>\n<th>\u5177\u4f53\u5e94\u7528<\/th>\n<th>\u50ac\u5316\u5242\u7528\u91cf (mol%)<\/th>\n<th>\u53cd\u5e94\u6e29\u5ea6 (\u00b0C)<\/th>\n<th>\u4ea7\u7269\u9009\u62e9\u6027 (%)<\/th>\n<th>\u5907\u6ce8<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u916f\u5316\u53cd\u5e94<\/td>\n<td>\u5408\u6210\u9999\u6599<\/td>\n<td>0.1 &#8211; 1<\/td>\n<td>80 &#8211; 120<\/td>\n<td>&gt;95<\/td>\n<td>\u63d0\u9ad8\u4ea7\u7387\uff0c\u7f29\u77ed\u53cd\u5e94\u65f6\u95f4<\/td>\n<\/tr>\n<tr>\n<td>\u52a0\u6c22\u53cd\u5e94<\/td>\n<td>\u5236\u5907\u805a\u6c28\u916f\u539f\u6599<\/td>\n<td>0.5 &#8211; 2<\/td>\n<td>100 &#8211; 150<\/td>\n<td>&gt;90<\/td>\n<td>\u63d0\u5347\u4ea7\u54c1\u7eaf\u5ea6\u548c\u6536\u7387<\/td>\n<\/tr>\n<tr>\n<td>\u805a\u5408\u53cd\u5e94<\/td>\n<td>\u751f\u7269\u964d\u89e3\u5851\u6599<\/td>\n<td>0.05 &#8211; 0.5<\/td>\n<td>120 &#8211; 180<\/td>\n<td>&gt;85<\/td>\n<td>\u63a7\u5236\u5206\u5b50\u91cf\u5206\u5e03\uff0c\u6539\u5584\u673a\u68b0\u6027\u80fd<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<hr>\n<p>\u8bf7\u6ce8\u610f\uff0c\u4e0a\u8ff0\u5185\u5bb9\u662f\u57fa\u4e8e\u5047\u8bbe\u6027\u7684\u7efc\u8ff0\u64b0\u5199\u800c\u6210\uff0c\u5b9e\u9645\u5e94\u7528\u4e2d\u5f02\u8f9b\u9178\u94cb\u7684\u5177\u4f53\u6027\u80fd\u53c2\u6570\u53ef\u80fd\u4f1a\u6709\u6240\u4e0d\u540c\uff0c\u5efa\u8bae\u67e5\u9605\u65b0\u7684\u79d1\u7814\u8d44\u6599\u4ee5\u83b7\u53d6\u51c6\u786e\u4fe1\u606f\u3002<\/p>\n<p>\u6269\u5c55\u9605\u8bfb\uff1a<br \/>\n<a href=\"https:\/\/www.cyclohexylamine.net\/dabco-mp608-delayed-equilibrium-catalyst\/\"><u>DABCO MP608\/Delayed equilibrium catalyst<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.cyclohexylamine.net\/teda-l33b-dabco-polycat-gel-catalyst\/\"><u>TEDA-L33B\/DABCO POLYCAT\/Gel catalyst<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.cyclohexylamine.net\/addocat-106-teda-l33b-dabco-polycat\/\"><u>Addocat 106\/TEDA-L33B\/DABCO POLYCAT<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.newtopchem.com\/archives\/103\"><u>NT CAT ZR-50<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.newtopchem.com\/archives\/100\"><u>NT CAT TMR-2<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.newtopchem.com\/archives\/97\"><u>NT CAT PC-77<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.morpholine.org\/dimethomorph\/\"><u>dimethomorph<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.morpholine.org\/3-morpholinopropylamine\/\"><u>3-morpholinopropylamine<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.bdmaee.net\/toyocat-np-catalyst-tosoh\/\">Toyocat NP catalyst Tosoh<\/a><\/p>\n<p><a href=\"https:\/\/www.bdmaee.net\/toyocat-ets-foaming-catalyst-tosoh\/\">Toyocat ETS Foaming catalyst Tosoh<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5f02\u8f9b\u9178\u94cb\u4f5c\u4e3a\u91d1\u5c5e\u50ac\u5316\u5242\u5728\u5316\u5b66\u5de5\u4e1a\u4e2d\u7684\u5e94\u7528 \u6458\u8981 \u5f02\u8f9b\u9178\u94cb\u662f\u4e00\u79cd\u91cd\u8981\u7684\u6709\u673a\u94cb\u5316\u5408\u7269\uff0c\u56e0\u5176\u72ec\u7279\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u5728\u5316\u5b66\u5de5\u4e1a\u4e2d\u88ab\u5e7f\u6cdb\u7528\u4f5c\u50ac\u5316\u5242\u3002\u672c\u6587\u7efc\u8ff0\u4e86\u5f02\u8f9b\u9178\u94cb\u4f5c\u4e3a\u91d1\u5c5e\u50ac\u5316\u5242\u5728\u4e0d\u540c\u5316\u5b66\u53cd\u5e94\u4e2d\u7684\u5e94\u7528\u5b9e\u4f8b\uff0c\u5305\u62ec\u4f46\u4e0d\u9650\u4e8e\u916f\u5316\u53cd\u5e94\u3001\u52a0\u6c22\u53cd\u5e94\u3001\u805a\u5408\u53cd\u5e94\u7b49\uff0c\u5e76\u5bf9\u5176\u50ac\u5316\u673a\u7406\u8fdb\u884c\u4e86\u7b80\u8981\u5206\u6790\u3002\u6b64\u5916\uff0c\u8fd8\u8ba8\u8bba\u4e86\u5f02\u8f9b\u9178\u94cb\u5728\u73af\u4fdd\u548c\u7ecf\u6d4e\u6027\u65b9\u9762\u7684\u4f18\u52bf\uff0c\u4ee5 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