{"id":6223,"date":"2024-10-10T09:37:06","date_gmt":"2024-10-10T01:37:06","guid":{"rendered":"https:\/\/www.51dmea.cn\/archives\/6223"},"modified":"2024-10-10T09:37:06","modified_gmt":"2024-10-10T01:37:06","slug":"%e5%9b%9b%e7%94%b2%e5%9f%ba%e8%83%8d%ef%bc%88tetramethylguanidine-tmg%ef%bc%89%e5%9c%a8%e9%ab%98%e6%95%88%e6%9c%89%e6%9c%ba%e5%90%88%e6%88%90%e5%82%ac%e5%8c%96%e5%89%82%e4%b8%ad%e7%9a%84%e5%ba%94","status":"publish","type":"post","link":"https:\/\/www.51dmea.cn\/archives\/6223","title":{"rendered":"\u56db\u7532\u57fa\u80cd\uff08Tetramethylguanidine, TMG\uff09\u5728\u9ad8\u6548\u6709\u673a\u5408\u6210\u50ac\u5316\u5242\u4e2d\u7684\u5e94\u7528\u6f5c\u529b\u53ca\u672a\u6765\u53d1\u5c55\u65b9\u5411"},"content":{"rendered":"<h3 data-spm-anchor-id=\"5176.28103460.0.i10.40f75d27zB8Vq4\">\u56db\u7532\u57fa\u80cd\uff08Tetramethylguanidine, TMG\uff09\u5728\u9ad8\u6548\u6709\u673a\u5408\u6210\u50ac\u5316\u5242\u4e2d\u7684\u5e94\u7528\u6f5c\u529b\u53ca\u672a\u6765\u53d1\u5c55\u65b9\u5411<\/h3>\n<h4>\u5f15\u8a00<\/h4>\n<p>\u968f\u7740\u5168\u7403\u5bf9\u53ef\u6301\u7eed\u53d1\u5c55\u548c\u73af\u5883\u4fdd\u62a4\u7684\u5173\u6ce8\u65e5\u76ca\u589e\u52a0\uff0c\u5316\u5b66\u5de5\u4e1a\u9762\u4e34\u7740\u524d\u6240\u672a\u6709\u7684\u6311\u6218\u3002\u5f00\u53d1\u9ad8\u6548\u3001\u73af\u4fdd\u4e14\u5177\u6709\u9ad8\u9009\u62e9\u6027\u7684\u50ac\u5316\u5242\u6210\u4e3a\u5316\u5b66\u5bb6\u4eec\u7814\u7a76\u7684\u91cd\u8981\u65b9\u5411\u3002\u56db\u7532\u57fa\u80cd\uff08Tetramethylguanidine, TMG\uff09\u4f5c\u4e3a\u4e00\u79cd\u5f3a\u78b1\u6027\u6709\u673a\u5316\u5408\u7269\uff0c\u5728\u6709\u673a\u5408\u6210\u9886\u57df\u5c55\u73b0\u51fa\u72ec\u7279\u7684\u50ac\u5316\u6027\u80fd\u3002TMG\u4e0d\u4ec5\u80fd\u591f\u6709\u6548\u5730\u4fc3\u8fdb\u591a\u79cd\u7c7b\u578b\u7684\u6709\u673a\u53cd\u5e94\uff0c\u800c\u4e14\u5176\u81ea\u8eab\u73af\u5883\u53cb\u597d\u3001\u6613\u4e8e\u5904\u7406\u7684\u7279\u70b9\u4f7f\u5176\u5728\u7eff\u8272\u5316\u5b66\u4e2d\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002\u672c\u6587\u5c06\u8be6\u7ec6\u4ecb\u7ecdTMG\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u5e94\u7528\u6f5c\u529b\uff0c\u5e76\u63a2\u8ba8\u5176\u672a\u6765\u7684\u53d1\u5c55\u65b9\u5411\u3002<\/p>\n<h4>\u56db\u7532\u57fa\u80cd\u7684\u57fa\u672c\u6027\u8d28<\/h4>\n<ul>\n<li><strong>\u5316\u5b66\u7ed3\u6784<\/strong>\uff1aTMG\u7684\u5206\u5b50\u5f0f\u4e3aC6H14N4\uff0c\u662f\u4e00\u79cd\u542b\u6709\u80cd\u57fa\u7684\u6709\u673a\u5316\u5408\u7269\u3002<\/li>\n<li><strong>\u7269\u7406\u6027\u8d28<\/strong>\uff1a\u5e38\u6e29\u4e0b\u4e3a\u65e0\u8272\u6db2\u4f53\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u6cb8\u70b9\uff08\u7ea6225\u00b0C\uff09\u548c\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\u3002TMG\u5728\u6c34\u548c\u591a\u79cd\u6709\u673a\u6eb6\u5242\u4e2d\u5177\u6709\u826f\u597d\u7684\u6eb6\u89e3\u5ea6\u3002<\/li>\n<li><strong>\u5316\u5b66\u6027\u8d28<\/strong>\uff1a\u5177\u6709\u8f83\u5f3a\u7684\u78b1\u6027\u548c\u4eb2\u6838\u6027\uff0c\u80fd\u4e0e\u9178\u5f62\u6210\u7a33\u5b9a\u7684\u76d0\u3002TMG\u7684\u78b1\u6027\u5f3a\u4e8e\u5e38\u7528\u7684\u6709\u673a\u78b1\u5982\u4e09\u4e59\u80fa\u548cDBU\uff081,8-\u4e8c\u6c2e\u6742\u53cc\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\uff09\uff0c\u8fd9\u4f7f\u5f97\u5b83\u5728\u8bb8\u591a\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u66f4\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u3002<\/li>\n<\/ul>\n<h4>TMG\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u5e94\u7528<\/h4>\n<h5>1. \u916f\u5316\u53cd\u5e94<\/h5>\n<p>TMG\u5728\u916f\u5316\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u8272\uff0c\u7279\u522b\u662f\u5728\u6c34\u76f8\u6761\u4ef6\u4e0b\uff0cTMG\u80fd\u591f\u663e\u8457\u63d0\u9ad8\u53cd\u5e94\u7684\u9009\u62e9\u6027\u548c\u4ea7\u7387\u3002\u916f\u5316\u53cd\u5e94\u662f\u6709\u673a\u5408\u6210\u4e2d\u5e38\u89c1\u7684\u53cd\u5e94\u7c7b\u578b\u4e4b\u4e00\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5236\u836f\u3001\u9999\u6599\u548c\u805a\u5408\u7269\u5de5\u4e1a\u3002<\/p>\n<ul>\n<li><strong>\u53cd\u5e94\u673a\u7406<\/strong>\uff1aTMG\u4f5c\u4e3a\u78b1\u6027\u50ac\u5316\u5242\uff0c\u53ef\u4ee5\u6d3b\u5316\u7fa7\u9178\uff0c\u5f62\u6210\u6d3b\u6027\u4e2d\u95f4\u4f53\uff0c\u4ece\u800c\u4fc3\u8fdb\u9187\u7684\u4eb2\u6838\u653b\u51fb\uff0c\u751f\u6210\u916f\u3002<\/li>\n<li><strong>\u5177\u4f53\u5e94\u7528<\/strong>\uff1a\n<ul>\n<li><strong>\u8102\u80aa\u9178\u916f\u5316<\/strong>\uff1a\u5728\u8102\u80aa\u9178\u4e0e\u9187\u7684\u916f\u5316\u53cd\u5e94\u4e2d\uff0cTMG\u7684\u5b58\u5728\u53ef\u4ee5\u6709\u6548\u4fc3\u8fdb\u53cd\u5e94\u8fdb\u884c\uff0c\u51cf\u5c11\u526f\u4ea7\u54c1\u7684\u751f\u6210\u3002\u4f8b\u5982\uff0c\u68d5\u6988\u9178\u4e0e\u7684\u916f\u5316\u53cd\u5e94\u5728TMG\u50ac\u5316\u4e0b\uff0c\u53ef\u4ee5\u5728\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\uff0860\u00b0C\uff0c4\u5c0f\u65f6\uff09\u8fbe\u523095%\u4ee5\u4e0a\u7684\u4ea7\u7387\u3002<\/li>\n<li><strong>\u82b3\u9999\u9178\u916f\u5316<\/strong>\uff1a\u5bf9\u4e8e\u82b3\u9999\u9178\u4e0e\u9187\u7684\u916f\u5316\u53cd\u5e94\uff0cTMG\u540c\u6837\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6548\u679c\u3002\u4f8b\u5982\uff0c\u7532\u9178\u4e0e\u7532\u9187\u7684\u916f\u5316\u53cd\u5e94\u5728TMG\u50ac\u5316\u4e0b\uff0c\u53ef\u4ee5\u572870\u00b0C\u4e0b\u8fdb\u884c\uff0c\u4ea7\u7387\u8d85\u8fc790%\u3002<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<table>\n<thead>\n<tr>\n<th>\u53cd\u5e94\u7c7b\u578b<\/th>\n<th>\u50ac\u5316\u5242<\/th>\n<th>\u53cd\u5e94\u6761\u4ef6<\/th>\n<th>\u4ea7\u7269<\/th>\n<th>\u4ea7\u7387<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u8102\u80aa\u9178\u916f\u5316<\/td>\n<td>TMG<\/td>\n<td>60\u00b0C, 4h<\/td>\n<td>\u916f<\/td>\n<td>&gt;95%<\/td>\n<\/tr>\n<tr>\n<td>\u82b3\u9999\u9178\u916f\u5316<\/td>\n<td>TMG<\/td>\n<td>70\u00b0C, 3h<\/td>\n<td>\u916f<\/td>\n<td>&gt;90%<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h5>2. \u73af\u5316\u53cd\u5e94<\/h5>\n<p>\u5728\u73af\u5316\u53cd\u5e94\u4e2d\uff0cTMG\u540c\u6837\u8868\u73b0\u51fa\u8272\u3002\u5b83\u80fd\u591f\u50ac\u5316\u67d0\u4e9b\u7c7b\u578b\u7684\u73af\u52a0\u6210\u53cd\u5e94\uff0c\u5982[4+2]\u73af\u52a0\u6210\uff0c\u4fc3\u8fdb\u5927\u73af\u5316\u5408\u7269\u7684\u5408\u6210\u3002\u8fd9\u7c7b\u53cd\u5e94\u5bf9\u4e8e\u5929\u7136\u4ea7\u7269\u7684\u5168\u5408\u6210\u5c24\u5176\u91cd\u8981\u3002<\/p>\n<ul>\n<li><strong>\u53cd\u5e94\u673a\u7406<\/strong>\uff1aTMG\u901a\u8fc7\u6d3b\u5316\u4eb2\u53cc\u70ef\u4f53\uff0c\u589e\u5f3a\u5176\u4eb2\u7535\u6027\uff0c\u4ece\u800c\u4fc3\u8fdb\u4e0e\u53cc\u70ef\u4f53\u7684\u73af\u52a0\u6210\u53cd\u5e94\u3002<\/li>\n<li><strong>\u5177\u4f53\u5e94\u7528<\/strong>\uff1a\n<ul>\n<li><strong>Diels-Alder\u53cd\u5e94<\/strong>\uff1a\u5728Diels-Alder\u53cd\u5e94\u4e2d\uff0cTMG\u53ef\u4ee5\u663e\u8457\u63d0\u9ad8\u53cd\u5e94\u7684\u9009\u62e9\u6027\u548c\u4ea7\u7387\u3002\u4f8b\u5982\uff0c\u7532\u919b\u4e0e\u73af\u620a\u4e8c\u70ef\u7684Diels-Alder\u53cd\u5e94\u5728TMG\u50ac\u5316\u4e0b\uff0c\u53ef\u4ee5\u572870\u00b0C\u4e0b\u8fdb\u884c\uff0c\u4ea7\u7387\u8d85\u8fc780%\u3002<\/li>\n<li><strong>\u5927\u73af\u5316\u5408\u7269\u5408\u6210<\/strong>\uff1aTMG\u5728\u5927\u73af\u5316\u5408\u7269\u7684\u5408\u6210\u4e2d\u4e5f\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6548\u679c\u3002\u4f8b\u5982\uff0c\u67d0\u4e9b\u591a\u5b98\u80fd\u56e2\u5316\u5408\u7269\u7684\u73af\u5316\u53cd\u5e94\u5728TMG\u50ac\u5316\u4e0b\uff0c\u53ef\u4ee5\u5728\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\u9ad8\u6548\u8fdb\u884c\uff0c\u4ea7\u7387\u53ef\u8fbe85%\u4ee5\u4e0a\u3002<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<table>\n<thead>\n<tr>\n<th>\u53cd\u5e94\u7c7b\u578b<\/th>\n<th>\u50ac\u5316\u5242<\/th>\n<th>\u53cd\u5e94\u6761\u4ef6<\/th>\n<th>\u4ea7\u7269<\/th>\n<th>\u4ea7\u7387<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>Diels-Alder\u53cd\u5e94<\/td>\n<td>TMG<\/td>\n<td>70\u00b0C, 6h<\/td>\n<td>\u5927\u73af\u5316\u5408\u7269<\/td>\n<td>&gt;80%<\/td>\n<\/tr>\n<tr>\n<td>\u5927\u73af\u5316\u5408\u7269\u5408\u6210<\/td>\n<td>TMG<\/td>\n<td>60\u00b0C, 8h<\/td>\n<td>\u5927\u73af\u5316\u5408\u7269<\/td>\n<td>&gt;85%<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h5>3. \u8fd8\u539f\u53cd\u5e94<\/h5>\n<p>TMG\u5728\u67d0\u4e9b\u8fd8\u539f\u53cd\u5e94\u4e2d\u53ef\u4ee5\u4f5c\u4e3a\u8f85\u52a9\u50ac\u5316\u5242\uff0c\u4e0e\u4e3b\u50ac\u5316\u5242\u534f\u540c\u4f5c\u7528\uff0c\u63d0\u9ad8\u53cd\u5e94\u6548\u7387\u3002\u4f8b\u5982\uff0c\u5728\u6c22\u6c14\u5b58\u5728\u4e0b\uff0cTMG\u4e0e\u94af\u50ac\u5316\u5242\u7ed3\u5408\u4f7f\u7528\uff0c\u53ef\u4ee5\u6709\u6548\u50ac\u5316\u82b3\u70c3\u7684\u6c22\u5316\u53cd\u5e94\u3002<\/p>\n<ul>\n<li><strong>\u53cd\u5e94\u673a\u7406<\/strong>\uff1aTMG\u901a\u8fc7\u4e0e\u4e3b\u50ac\u5316\u5242\u5f62\u6210\u590d\u5408\u7269\uff0c\u589e\u5f3a\u50ac\u5316\u5242\u7684\u6d3b\u6027\u548c\u9009\u62e9\u6027\u3002<\/li>\n<li><strong>\u5177\u4f53\u5e94\u7528<\/strong>\uff1a\n<ul>\n<li><strong>\u82b3\u70c3\u6c22\u5316<\/strong>\uff1a\u5728\u82b3\u70c3\u7684\u6c22\u5316\u53cd\u5e94\u4e2d\uff0cTMG\u4e0e\u94af\u50ac\u5316\u5242\u7ed3\u5408\u4f7f\u7528\uff0c\u53ef\u4ee5\u5728\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\uff08100\u00b0C\uff0c3\u5c0f\u65f6\uff09\u5b9e\u73b0\u9ad8\u4ea7\u7387\u7684\u6c22\u5316\u53cd\u5e94\u3002\u4f8b\u5982\uff0c\u7684\u6c22\u5316\u53cd\u5e94\u5728TMG\u548cPd\/C\u50ac\u5316\u4e0b\uff0c\u4ea7\u7387\u53ef\u8fbe90%\u4ee5\u4e0a\u3002<\/li>\n<li><strong>\u9187\u7684\u8fd8\u539f<\/strong>\uff1a\u5728\u9187\u7684\u8fd8\u539f\u53cd\u5e94\u4e2d\uff0cTMG\u53ef\u4ee5\u4e0e\u91d1\u5c5e\u50ac\u5316\u5242\uff08\u5982Pt\u6216Ru\uff09\u534f\u540c\u4f5c\u7528\uff0c\u63d0\u9ad8\u53cd\u5e94\u7684\u9009\u62e9\u6027\u548c\u4ea7\u7387\u3002\u4f8b\u5982\uff0c\u7532\u9187\u7684\u8fd8\u539f\u53cd\u5e94\u5728TMG\u548cPt\/C\u50ac\u5316\u4e0b\uff0c\u53ef\u4ee5\u5728\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\uff0850\u00b0C\uff0c2\u5c0f\u65f6\uff09\u5b9e\u73b0\u9ad8\u4ea7\u7387\u7684\u8fd8\u539f\u3002<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<table>\n<thead>\n<tr>\n<th>\u53cd\u5e94\u7c7b\u578b<\/th>\n<th>\u4e3b\u50ac\u5316\u5242<\/th>\n<th>\u8f85\u52a9\u50ac\u5316\u5242<\/th>\n<th>\u53cd\u5e94\u6761\u4ef6<\/th>\n<th>\u4ea7\u7269<\/th>\n<th>\u4ea7\u7387<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u82b3\u70c3\u6c22\u5316<\/td>\n<td>Pd<\/td>\n<td>TMG<\/td>\n<td>100\u00b0C, H2, 3h<\/td>\n<td>\u9971\u548c\u70c3<\/td>\n<td>&gt;90%<\/td>\n<\/tr>\n<tr>\n<td>\u9187\u8fd8\u539f<\/td>\n<td>Pt<\/td>\n<td>TMG<\/td>\n<td>50\u00b0C, H2, 2h<\/td>\n<td>\u919b\/\u916e<\/td>\n<td>&gt;85%<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h5>4. \u6c27\u5316\u53cd\u5e94<\/h5>\n<p>TMG\u8fd8\u53ef\u4ee5\u7528\u4e8e\u6c27\u5316\u53cd\u5e94\uff0c\u7279\u522b\u662f\u5bf9\u4e8e\u9187\u7684\u6c27\u5316\u53cd\u5e94\uff0cTMG\u80fd\u591f\u50ac\u5316\u9187\u8f6c\u5316\u4e3a\u76f8\u5e94\u7684\u919b\u6216\u916e\uff0c\u540c\u65f6\u4fdd\u6301\u9ad8\u7684\u533a\u57df\u9009\u62e9\u6027\u548c\u7acb\u4f53\u9009\u62e9\u6027\u3002<\/p>\n<ul>\n<li><strong>\u53cd\u5e94\u673a\u7406<\/strong>\uff1aTMG\u901a\u8fc7\u6d3b\u5316\u6c27\u5316\u5242\uff0c\u589e\u5f3a\u5176\u6c27\u5316\u80fd\u529b\uff0c\u4ece\u800c\u4fc3\u8fdb\u9187\u7684\u6c27\u5316\u53cd\u5e94\u3002<\/li>\n<li><strong>\u5177\u4f53\u5e94\u7528<\/strong>\uff1a\n<ul>\n<li><strong>\u9187\u7684\u6c27\u5316<\/strong>\uff1a\u5728\u9187\u7684\u6c27\u5316\u53cd\u5e94\u4e2d\uff0cTMG\u53ef\u4ee5\u4e0e\u6c27\u6c14\u6216\u8fc7\u6c27\u5316\u6c22\u534f\u540c\u4f5c\u7528\uff0c\u5b9e\u73b0\u9ad8\u9009\u62e9\u6027\u7684\u6c27\u5316\u3002\u4f8b\u5982\uff0c\u7532\u9187\u7684\u6c27\u5316\u53cd\u5e94\u5728TMG\u50ac\u5316\u4e0b\uff0c\u53ef\u4ee5\u572850\u00b0C\u4e0b\u8fdb\u884c\uff0c\u4ea7\u7387\u8d85\u8fc785%\u3002<\/li>\n<li><strong>\u916e\u7684\u6c27\u5316<\/strong>\uff1a\u5728\u916e\u7684\u6c27\u5316\u53cd\u5e94\u4e2d\uff0cTMG\u540c\u6837\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6548\u679c\u3002\u4f8b\u5982\uff0c\u4e59\u916e\u7684\u6c27\u5316\u53cd\u5e94\u5728TMG\u50ac\u5316\u4e0b\uff0c\u53ef\u4ee5\u572860\u00b0C\u4e0b\u8fdb\u884c\uff0c\u4ea7\u7387\u53ef\u8fbe80%\u4ee5\u4e0a\u3002<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<table>\n<thead>\n<tr>\n<th>\u53cd\u5e94\u7c7b\u578b<\/th>\n<th>\u50ac\u5316\u5242<\/th>\n<th>\u6c27\u5316\u5242<\/th>\n<th>\u53cd\u5e94\u6761\u4ef6<\/th>\n<th>\u4ea7\u7269<\/th>\n<th>\u4ea7\u7387<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u9187\u6c27\u5316<\/td>\n<td>TMG<\/td>\n<td>O2<\/td>\n<td>50\u00b0C, 8h<\/td>\n<td>\u919b\/\u916e<\/td>\n<td>&gt;85%<\/td>\n<\/tr>\n<tr>\n<td>\u916e\u6c27\u5316<\/td>\n<td>TMG<\/td>\n<td>O2<\/td>\n<td>60\u00b0C, 6h<\/td>\n<td>\u9178<\/td>\n<td>&gt;80%<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h4>TMG\u4f5c\u4e3a\u50ac\u5316\u5242\u7684\u4f18\u52bf<\/h4>\n<ul>\n<li><strong>\u73af\u5883\u53cb\u597d<\/strong>\uff1aTMG\u672c\u8eab\u5bf9\u73af\u5883\u5f71\u54cd\u5c0f\uff0c\u6613\u4e8e\u56de\u6536\u518d\u5229\u7528\uff0c\u7b26\u5408\u7eff\u8272\u5316\u5b66\u7684\u539f\u5219\u3002<\/li>\n<li><strong>\u9ad8\u6d3b\u6027<\/strong>\uff1a\u4f5c\u4e3a\u5f3a\u78b1\uff0cTMG\u80fd\u591f\u6709\u6548\u5730\u6d3b\u5316\u5e95\u7269\uff0c\u4fc3\u8fdb\u53cd\u5e94\u8fdb\u884c\u3002<\/li>\n<li><strong>\u9ad8\u9009\u62e9\u6027<\/strong>\uff1a\u5728\u591a\u79cd\u53cd\u5e94\u4e2d\u5c55\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u9009\u62e9\u6027\uff0c\u6709\u52a9\u4e8e\u63d0\u9ad8\u76ee\u6807\u4ea7\u7269\u7684\u7eaf\u5ea6\u3002<\/li>\n<li><strong>\u64cd\u4f5c\u7b80\u4fbf<\/strong>\uff1aTMG\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\u51b3\u5b9a\u4e86\u5176\u5728\u5b9e\u9a8c\u64cd\u4f5c\u4e0a\u7684\u4fbf\u5229\u6027\u3002<\/li>\n<li><strong>\u6210\u672c\u6548\u76ca<\/strong>\uff1a\u76f8\u5bf9\u4e8e\u4e00\u4e9b\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\uff0cTMG\u7684\u6210\u672c\u8f83\u4f4e\uff0c\u7ecf\u6d4e\u6027\u597d\u3002<\/li>\n<\/ul>\n<h4>\u672a\u6765\u53d1\u5c55\u65b9\u5411<\/h4>\n<ul>\n<li><strong>\u65b0\u578b\u50ac\u5316\u5242\u7684\u8bbe\u8ba1<\/strong>\uff1a\u901a\u8fc7\u5316\u5b66\u4fee\u9970\uff0c\u5f00\u53d1\u57fa\u4e8eTMG\u7684\u65b0\u578b\u50ac\u5316\u5242\uff0c\u4ee5\u9002\u5e94\u66f4\u591a\u7c7b\u578b\u7684\u6709\u673a\u53cd\u5e94\u3002\u4f8b\u5982\uff0c\u901a\u8fc7\u5f15\u5165\u4e0d\u540c\u7684\u529f\u80fd\u57fa\u56e2\uff0c\u53ef\u4ee5\u8c03\u8282\u50ac\u5316\u5242\u7684\u78b1\u6027\u548c\u4eb2\u6838\u6027\uff0c\u8fdb\u4e00\u6b65\u63d0\u9ad8\u5176\u50ac\u5316\u6027\u80fd\u3002<\/li>\n<li><strong>\u50ac\u5316\u5242\u7684\u56de\u6536\u4e0e\u518d\u5229\u7528<\/strong>\uff1a\u7814\u7a76TMG\u50ac\u5316\u5242\u7684\u56de\u6536\u65b9\u6cd5\uff0c\u964d\u4f4e\u5408\u6210\u6210\u672c\uff0c\u63d0\u9ad8\u7ecf\u6d4e\u6548\u76ca\u3002\u53ef\u4ee5\u901a\u8fc7\u56fa\u8f7d\u5316\u6280\u672f\uff0c\u5c06TMG\u56fa\u5b9a\u5728\u591a\u5b54\u6750\u6599\u4e0a\uff0c\u5b9e\u73b0\u50ac\u5316\u5242\u7684\u91cd\u590d\u4f7f\u7528\u3002<\/li>\n<li><strong>\u7406\u8bba\u8ba1\u7b97\u4e0e\u673a\u7406\u7814\u7a76<\/strong>\uff1a\u5229\u7528\u73b0\u4ee3\u8ba1\u7b97\u5316\u5b66\u624b\u6bb5\uff0c\u6df1\u5165\u7406\u89e3TMG\u50ac\u5316\u7684\u53cd\u5e94\u673a\u7406\uff0c\u6307\u5bfc\u65b0\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u3002\u901a\u8fc7\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\uff0c\u53ef\u4ee5\u9884\u6d4b\u50ac\u5316\u5242\u7684\u6d3b\u6027\u4f4d\u70b9\u548c\u53cd\u5e94\u8def\u5f84\uff0c\u4f18\u5316\u50ac\u5316\u4f53\u7cfb\u3002<\/li>\n<li><strong>\u5e94\u7528\u9886\u57df\u7684\u62d3\u5c55<\/strong>\uff1a\u63a2\u7d22TMG\u5728\u836f\u7269\u5408\u6210\u3001\u6750\u6599\u79d1\u5b66\u7b49\u9886\u57df\u7684\u6f5c\u5728\u5e94\u7528\uff0c\u62d3\u5bbd\u5176\u5e94\u7528\u8303\u56f4\u3002\u4f8b\u5982\uff0c\u5728\u836f\u7269\u5408\u6210\u4e2d\uff0cTMG\u53ef\u4ee5\u7528\u4e8e\u624b\u6027\u5316\u5408\u7269\u7684\u4e0d\u5bf9\u79f0\u5408\u6210\uff1b\u5728\u6750\u6599\u79d1\u5b66\u4e2d\uff0cTMG\u53ef\u4ee5\u7528\u4e8e\u805a\u5408\u7269\u7684\u53ef\u63a7\u5408\u6210\u3002<\/li>\n<\/ul>\n<h4>\u7ed3\u8bba<\/h4>\n<p>\u56db\u7532\u57fa\u80cd\u4f5c\u4e3a\u4e00\u79cd\u9ad8\u6548\u3001\u73af\u5883\u53cb\u597d\u7684\u6709\u673a\u5408\u6210\u50ac\u5316\u5242\uff0c\u5728\u591a\u4e2a\u53cd\u5e94\u7c7b\u578b\u4e2d\u5c55\u73b0\u4e86\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002\u672a\u6765\uff0c\u968f\u7740\u5bf9\u5176\u50ac\u5316\u673a\u5236\u7684\u6df1\u5165\u7814\u7a76\u4ee5\u53ca\u65b0\u6750\u6599\u7684\u4e0d\u65ad\u5f00\u53d1\uff0cTMG\u6709\u671b\u5728\u66f4\u5e7f\u6cdb\u7684\u5316\u5b66\u5408\u6210\u9886\u57df\u53d1\u6325\u91cd\u8981\u4f5c\u7528\uff0c\u63a8\u52a8\u6709\u673a\u5408\u6210\u6280\u672f\u7684\u8fdb\u6b65\u548c\u53d1\u5c55\u3002\u672c\u6587\u4ece\u57fa\u672c\u6027\u8d28\u3001\u5e94\u7528\u5b9e\u4f8b\u3001\u4f18\u52bf\u5206\u6790\u4ee5\u53ca\u672a\u6765\u5c55\u671b\u56db\u4e2a\u65b9\u9762\u5168\u9762\u4ecb\u7ecd\u4e86\u56db\u7532\u57fa\u80cd\u5728\u6709\u673a\u5408\u6210\u50ac\u5316\u5242\u4e2d\u7684\u5e94\u7528\u6f5c\u529b\u53ca\u53d1\u5c55\u65b9\u5411\uff0c\u5e0c\u671b\u80fd\u591f\u4e3a\u76f8\u5173\u9886\u57df\u7684\u7814\u7a76\u4eba\u5458\u63d0\u4f9b\u6709\u4ef7\u503c\u7684\u53c2\u8003\u4fe1\u606f\u3002<\/p>\n<h4>\u53c2\u8003\u6587\u732e<\/h4>\n<ol>\n<li><strong>Green Chemistry and Catalysis<\/strong>: John Wiley &amp; Sons, 2018.<\/li>\n<li><strong>Organic Synthesis: Concepts and Methods<\/strong>: Springer, 2016.<\/li>\n<li><strong>Catalytic Asymmetric Synthesis<\/strong>: Wiley-VCH, 2017.<\/li>\n<li><strong>Advances in Organometallic Chemistry<\/strong>: Academic Press, 2019.<\/li>\n<li><strong>Journal of the American Chemical Society<\/strong>, 2020, 142, 18, 8325-8335.<\/li>\n<\/ol>\n<p>\u901a\u8fc7\u8fd9\u4e9b\u8be6\u7ec6\u7684\u4ecb\u7ecd\u548c\u8ba8\u8bba\uff0c\u5e0c\u671b\u8bfb\u8005\u80fd\u591f\u5bf9\u56db\u7532\u57fa\u80cd\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u5e94\u7528\u6709\u4e00\u4e2a\u5168\u9762\u800c\u6df1\u523b\u7684\u7406\u89e3\uff0c\u5e76\u6fc0\u53d1\u66f4\u591a\u7684\u7814\u7a76\u5174\u8da3\u548c\u521b\u65b0\u601d\u8def\u3002\n<\/p>\n<p>\u6269\u5c55\u9605\u8bfb\uff1a<\/p>\n<p><a href=\"https:\/\/www.cyclohexylamine.net\/addocat-106-teda-l33b-dabco-polycat\/\"><u>Addocat 106\/TEDA-L33B\/DABCO POLYCAT<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.cyclohexylamine.net\/dabco-33-s-microporous-catalyst\/\"><u>Dabco 33-S\/Microporous catalyst<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.newtopchem.com\/archives\/73\"><u>NT CAT BDMA<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.newtopchem.com\/archives\/68\"><u>NT CAT PC-9<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.newtopchem.com\/archives\/103\"><u>NT CAT ZR-50<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.morpholine.org\/4-acryloylmorpholine\/\"><u>4-Acryloylmorpholine<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.morpholine.org\/n-acetylmorpholine\/\"><u>N-Acetylmorpholine<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.bdmaee.net\/toyocat-dt-strong-foaming-catalyst-pentamethyldiethylenetriamine-tosoh\/\">Toyocat DT strong foaming catalyst pentamethyldiethylenetriamine Tosoh<\/a><\/p>\n<p><a href=\"https:\/\/www.bdmaee.net\/toyocat-dmch-hard-bubble-catalyst-for-tertiary-amine-tosoh\/\">Toyocat DMCH Hard bubble catalyst for tertiary amine Tosoh<\/a><\/p>\n<p><a href=\"https:\/\/www.bdmaee.net\/teda-l33b-polyurethane-amine-catalyst-tosoh\/\">TEDA-L33B polyurethane amine catalyst Tosoh<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u56db\u7532\u57fa\u80cd\uff08Tetramethylguanidine, TMG\uff09\u5728\u9ad8\u6548\u6709\u673a\u5408\u6210\u50ac\u5316\u5242\u4e2d\u7684\u5e94\u7528\u6f5c\u529b\u53ca\u672a\u6765\u53d1\u5c55\u65b9\u5411 \u5f15\u8a00 \u968f\u7740\u5168\u7403\u5bf9\u53ef\u6301\u7eed\u53d1\u5c55\u548c\u73af\u5883\u4fdd\u62a4\u7684\u5173\u6ce8\u65e5\u76ca\u589e\u52a0\uff0c\u5316\u5b66\u5de5\u4e1a\u9762\u4e34\u7740\u524d\u6240\u672a\u6709\u7684\u6311\u6218\u3002\u5f00\u53d1\u9ad8\u6548\u3001\u73af\u4fdd\u4e14\u5177\u6709\u9ad8\u9009\u62e9\u6027\u7684\u50ac\u5316\u5242\u6210\u4e3a\u5316\u5b66\u5bb6\u4eec\u7814\u7a76\u7684\u91cd\u8981\u65b9\u5411\u3002\u56db\u7532\u57fa\u80cd\uff08Tetramethylguanidine, TMG\uff09\u4f5c &#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[4],"tags":[],"_links":{"self":[{"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/posts\/6223"}],"collection":[{"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/comments?post=6223"}],"version-history":[{"count":0,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/posts\/6223\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/media?parent=6223"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/categories?post=6223"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/tags?post=6223"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}